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meixinjiance
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- 2015-03-11
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发表于 2015-03-17 17:23
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不锈钢304牌号鉴定1、案例背景5ò±eT"
ÿ>bbs.3c3t.com¢4,ÑuaÊí¹Ò该不锈钢产品的使用领域的食品接触材料领域,产品主要用于制作汤锅、水壶等。委托方要求分析该材料是否符合美国标准ASTM A276-2013 304牌号的要求,以确定其所使用的材料是符合《GB 9684-88 不锈钢食具容器卫生标准》条款。5ò±eT"
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ÿ>bbs.3c3t.com¢4,ÑuaÊí¹Ò 5ò±eT"
ÿ>bbs.3c3t.com¢4,ÑuaÊí¹Ò2、分析方法简述5ò±eT"
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ÿ>bbs.3c3t.com¢4,ÑuaÊí¹Òa、对样品进行XRF半定量分析,分析结果如下:5ò±eT"
ÿ>bbs.3c3t.com¢4,ÑuaÊí¹Ò5ò±eT"
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| 含量5ò±eT"
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| 1.05%5ò±eT"
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| 18.01%5ò±eT"
ÿ>bbs.3c3t.com¢4,ÑuaÊí¹Ò 5ò±eT"
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| 8.02%5ò±eT"
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| 0.10%5ò±eT"
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| 0.23%5ò±eT"
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| 从XRF定性半定量结果上分析,初步可以判定该材料应属于GB 9684-88所规定的奥氏体不锈钢。于是参考不锈钢分析标准对材料进行准确定量分析。5ò±eT"
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ÿ>bbs.3c3t.com¢4,ÑuaÊí¹Òb、依据《GB/T 20123-2006 钢铁 总碳硫含量的测定 高频感应炉燃烧后红外吸收法(常规方法)》,采用纳克CS3000碳硫分析仪对该材料进行C和S含量分析,结果如下:5ò±eT"
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ÿ>bbs.3c3t.com¢4,ÑuaÊí¹Ò元素5ò±eT"
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| 含量5ò±eT"
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| 0.065%5ò±eT"
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| 0.018%5ò±eT"
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|
5ò±eT"
ÿ>bbs.3c3t.com¢4,ÑuaÊí¹Òc、依据《JIS G1258-2-2007 中文版 铁及钢—ICP发光光谱分析方法—第2部:锰、镍、铬、钼、铜、钨、钒、钴、钛及铌定量方法—硫酸磷酸分解法》,采用OPTIMA8000对该材料进行Si、Mn、P、Cr、Ni、Cu、Mo等元素进行定量分析,结果如下:5ò±eT"
ÿ>bbs.3c3t.com¢4,ÑuaÊí¹Ò元素5ò±eT"
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| 含量5ò±eT"
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| 0.587%5ò±eT"
ÿ>bbs.3c3t.com¢4,ÑuaÊí¹Ò 5ò±eT"
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| 1.15%5ò±eT"
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| 0.035%5ò±eT"
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| 18.28%5ò±eT"
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| 8.34%5ò±eT"
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| 0.43%5ò±eT"
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| 0.21%5ò±eT"
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ÿ>bbs.3c3t.com¢4,ÑuaÊí¹Ò3、结果分析与讨论5ò±eT"
ÿ>bbs.3c3t.com¢4,ÑuaÊí¹Ò 通过对该不锈钢材料进行成分分析,并对照ASTM A276-2013 304不锈钢材料成分含量要求发现,该不锈钢材料符合304不锈钢要求,属于《GB 9684-88 不锈钢食具容器卫生标准》所要求的奥氏体不锈钢。5ò±eT"
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元素5ò±eT"
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| 材料成分含量5ò±eT"
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| 304牌号成分要求5ò±eT"
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| 0.065%5ò±eT"
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| 0.08%5ò±eT"
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| 0.018%5ò±eT"
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| 0.030%5ò±eT"
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| 0.587%5ò±eT"
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| 1.00%5ò±eT"
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| 1.15%5ò±eT"
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| 0.045%5ò±eT"
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| 18.0%-20.0%5ò±eT"
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| 8.0%-11.0%5ò±eT"
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| —5ò±eT"
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| 余量5ò±eT"
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4、参考标准5ò±eT"
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GB/T 20123-2006 钢铁 总碳硫含量的测定 高频感应炉燃烧后红外吸收法(常规方法)5ò±eT"
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JIS G1258-2-2007 中文版 铁及钢—ICP发光光谱分析方法—第2部:锰、镍、铬、钼、铜、钨、钒、钴、钛及铌定量方法—硫酸磷酸分解法5ò±eT"
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